Questions solid
state physics
1
2
3
:
15 - The base vectors of the reciprocal lattice and their connection with the base vectors of the
corresponding real lattice
- The properties of the reciprocal lattice
76 - Miller indexes
17 Diffraction
: - X-rays, neutrons and electrons: discuss the kind of information that they can give if used as probes
in diffraction experiments
- The Von Laue condition for diffraction
- The Bragg condition and its physical assumptions (and why they are not reasonable)
20 - Equivalence of Von Laue and Bragg condition
21 - The Ewald sphere and the various kind of diffraction experimental techniques
22 Lattice oscillations
- The dynamical equation of the lattice oscillations and their solutions.
23 - What is a phonon dispersion relation
: - Discuss the oscillations of a linear chain of equal atoms
- Discuss the oscillations of a linear chain of two different atoms.
26 - Acoustical and optical modes of oscillation of a lattice.
27 - Measurement of the phonon dispersion relations.
: - The conservation of the crystal momentum: its meaning and the difference with respect to the
conservation of momentum.
- The density of states of the lattice oscillations
30 Specific heats
37 - Quantization of lattice oscillations
- The need of a quantum model for explaining the temperature dependence of the specific heat
32 - The Einstein model of the specific heat
33 - The Debye model of the specific heat
34 Thermal conductivity
- Why the thermal conductivity of a perfect harmonic lattice in infinite
35 - The phenomenological aspects of the temperature dependence of thermal conductivity in solids
36 - How to model thermal conductivity and the role of scattering
37 - Phonon phonon interaction
38 - Normal and umklapp processes and their role in thermal conductivity
39 Bloch theorem
- Approximations in modeling the electron states in a solid
: - Bloch waves: their physical interpretation
- How to demonstrate the Bloch theorem working in the real space
: - How to demonstrate the Bloch theorem working in the reciprocal space
- Periodicity of the electron states in a solid in the reciprocal space
: - The energy bands
- The nearly free electron model
÷ - The tight binding model
- The Fermi surface
48 comparisse
* electron states phonons
-
Electron transport
- The basic ingredients of the semiclassical model of electron transport in solids
49 - The concept of effective mass
50 - Describe the Bloch oscillations and why it is usually impossible to observe them
51 Superconductivity
- The most relevant aspects of superconductivity
52 - The Landau Ginzburg theory of superconductivity
53 - The basic assumptions of the BCS theory of superconductivity
54 implicazioni
Liouville theomem its
1 and
s
. physics
statistical
in
In Liouville '
the
write
andere to s
to
theater Gibbs
define the
head
we
firrst
ensemble :*
•
. :
I
of
The Gibbs set
ensemble is a s ,
by
Independent systems rreprresented
the
differente in
points phase space ,
(
coincide
density for
whose unless an
with distribution
the
constant )
arlitmary plq
function )
p .
,
time point
As in
each
goes.by mores
, collective
that the
phase
the Space so
.
rresernbles
motion of
the gas
a
are ,
interaction
collision
urithout
but on
any
pontiche
the "
Lehman " .
with descriptio
this
Using i.mn the
. the
write
of we
gas can
a , equation
continuity :
as E
¥ ( 0
D. speed
+ = :
p
-
- flow
variation
time point balance
of in a
p
in sporca
equilibrium firrst is
at the team zero ,
,
with
learning :
us
( 0
p =
p
.
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this p q
using Emmalin
Hamiltoniana
the we
,
got : È
È :p
)
È
& ¥
( 0
+ = =
. .
. REM
LIOUVILLE ' THEO
S
È i
è
since ¥
+
=
#
¥ i
= O
= function is
distribution
The p in
trrarjectory
constant alang any
the phase space . incomprensibile
( behave like
points
→ an
fluidi
meae
ON
IMPLICATI S : the
since to
system be
assume
• we
determinista tsnajechomies cannot
trrarjectozy
each offer and
cross a point
through
cannot the name
pass loop
it'
Arvire closed
nnsless a
s .
since Eff tenere
¥ and zero
• ama are
,
in the
ahtrnachants phase space
no .
points
csnhaining the
element
an
• its
di shape
dqdp changa
=p can dpd
its dqndp
volume
but ( dq
not = e
,
toovjectorias
systems
In the
Complex
• storage
defend
in the phase space
conditions
the initial
on .
that
demonstrrated it
it be
( can )
frractal
becomes a
constant
p
• p = papa lui logarithsn
pd is
lnlp ) lnl
pi
= +
. additive
(E) )
f- ftp.q
not
p = ,
stile
Liouville Shearer walid
is
The s
• in Mechanics
quantum the phase
,
quantized
just becomes
space .
canonical
minimo Canonical and
* , ensemble
nominal
gnanca | Grchange
cachange onlt and
energy
energy parrticles
definition
Statistical entropy
of
2 .
Definition nricrrocanonical ensembles
for
constant
with :
energy IT pontina
S ( of
ln ST ) :
= phase space
Properties : di
for
additive SI
quantita DI
i. =
• e.
, ,
S Si Se
+
= equilibrium
macroscopico the
fan
• ,
microstati
volume ST the largest
of is
equilibrium
snarimized
S at
qnantizing
34 phase
the space we can
,
statistical Weight
define the
the as
porzione
volume phase
of of space
a
by microstato
of
evpressed the number
it container . generali
Using 5 when
=
p we can se
the constant
not
is :
as
energy
§ lupi
5 lupi
< >
=
p
= -
- i be
S the
defries through Gibbs
also
can
formula : (
S WLÉ
dt )
1-
ln la in
system of
=p
=
= ore
È )
( ST states
the
w
(E)
= - w
E lnwn
= un
- the that
psnohability
is
rubare the
un microstato
the
is in
state n .
statistical
the
that
It le prover
con thernmodynsnmie
the
and entropy
entropy definition the
of
smo sama
are usesl
since be
Goth
they
Shing can
,
Lezione dinamica
the thermo
ho
quantità .
distribution
Gibbs
3 . giving definition
by
start
Let' of
s a
ensemble
Canonical :
CANONICAL ENSEMBLE
. ✓
Constant volume
SUBSYSTEM Total Eo
☐ :
energy
AMBIENT has
The in
is
subsystem En and
energy
equilibrium the ambiente
thermal with .
E E
E = -
ambient n
a
Let' the
to " Subsystem
"
freeze
s suppose
non learning ambient
the
at En
energy , likes
it
evolve
to
free as .
statistical ambient
weight the
di of
' : "
is
subsystem
the "
frozen
token .
. En
the
at energy .
to
work of
expression
We write wn
on ,
prestabilite fiend the Subsystem
to
the
at En
energy . A
'
A constant
DT
un :
= '
è the
' ambient
a entropy of
S
= :
'
S ' si
ln
= S' ( )
E E
= - n
. series
Taylor
'
5
Ecpanding assuming
as a ,
E
En « :
• È
(
( lei
s' S'
Eni È
e )
= -
- ?
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' En
5 )
( e T
f- temperatura
= - :
.
'
è
A
=
un "
è "
E
est Ed è
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= which into
È you
"
A e-
= CANONICALI DISTRIBUTION
(
GIBBS
Partition
4 function the canonical
in
. ensemble distribution
Gibbs
the
Given È
e-
A
=
un nommalization
impose the
we can
condition calcolate Constant
and the
abhaining
A :
, È
e-
E
Z
la = = partition
canonicale
is
which called "
function with
indicato the
and
"
-2
lettere "
" Zustansumrne
from the german
, .
contorni
This Z the
all
function about
microscopio information the
system write
allowing to the meam
us
, quantita
phpsical
of
value as :
any
E
f- fn
un
= F-
e-
E fa
¥
= also
It Med gira
to
be new
can a
the
definition entropy
of . formula
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the :
wnlnwn
E
S = - ET
ln Z t
= free
Helmholtz
Icing the F
energy
defend :
as
f- E TS
= - write :
we can
f- lait
T
= - represents between
this bridge
a
thermodynam.ve quantita
a ,
Helmholtz free
the energy
macroscopici microscopio
and the
( ,
Information Z
container in
s .
also
We rredefine Wa :
as
can )
el
=
un The distribution
Boltzmann for
5 . physics
perfecto and its
gas
a
meaning
set classica
consideri perfecta gas
us a ,
particle which
compound by have
each
Interaction other
with
no which Maguires that
rvhahsserrern , .
the the
dilated and
partidos are in
pontiche
of
number any
cvvemage smoller Shan
level is muck
energy le
K
a- 1
«
:
ore a . each
In this considera
case we can
particle isolato
calmati in
subsystem
as an
equilibrium the
with athens .
Gibbs distribution
the
use
we can psnobalility
We fore write
theme the
can .
particle has i.m
that value
a
a the Boltzmann
E
of as
energy a
Èstato : ¥ ¥
[
è e-
1 Z
= =
Wpa poverina
Epatica similare
looks
although the
it nera ,
is differente
distribution
Boltzmann since
the Gibbs
from distribution ,
single partiche
of
E the
is energy a
a ,
distribution
Gibbs
White in the
E n arrbitmary
of subsystem
the
is energy an ,
and include Interaction
would also sone
partiche
lecturer the .
The that
distribution
Boltzmann shows
of
the the state the
lower energy a ,
prestabilite particle
for
the
higham a
it and number
in the
be
to arremage
in
particle level
centinaia
of a can
Calculated
be as :
¥
è
è c
=
a affaires
constant la
is
urlare ( a N partidos
imposing £ ( )
of
#
=
ma .
distribution
Statistical perfecta
6 for a
. quantum gas
quantum is
perfecta
a wheal
gas gas
a
interaction pontiche
only behucen
the quantum effects
the
are for
1
the apprroximation Tra < < walid
classica
perfecto is not
gases
home pv
potential D= Tlnz
Landau
the
Writing = -
-
level
particular he
fare :
a -2
T ln
da = a
- ± )
ten N
e-
( E
= → na
- En E
na → panca
se
,
idepending values
the of hee can
we
on scenario
have possible
3 :
1) Fermione gas )
}
{ ( è
da ln
T
0,1 1 +
c-
ha = -
sta à the
fiend
Hsing = - we can
d µ
of particle level
in fa
number :
arerrage
sta 1
^ E
= [
È FERMI DI RAC
-
+
e
2) bassa gas È
'
Èi
( )
IN ten
da
c- =
ha e
-
the
andere
In series to
for be
0
convergente neesl <
ne µ .
'
( )
ten
da 1
= e
-
- particle level
of
number
Average in
fa :
sta 1 BOSE-EINSTEIN
= È
e- e
-
3) bofh 2)
If in the
1) and
casa
evpsnential team greaser
is mucho
abbaia
thorn :
ne
ore ,
tra BOLTZMANN
= e
The of
equation
F. of state perfecta
a
quantum gas
The Ilelmholtz quantum
free of
energy a
is by
given :
gas È N' È
Faaszmann fermioni
F ± +
= :
mi
"
2g VT " bosons
:
-
\/ 2s -11
F classica =
of g ↳ spin
gas È È )
N' EQUATION States
(
Nyt OF
±
1
= =
p
- GAS
Quantum
of
%
T
2g su ( )
pv NRT
a =
This that for fermione the
shows , classica
higham
is for
Shan
pressore
partidos repulsive Interaction
( ) ,
White bossa it is
for lower
attuative interaction )
( .
Refining the ehemical-pohential.us
È
=
µ sir following
the
state :
can
we partidos
Classica
• particle releases
addingane energy
kt
0
<
µ
Fermi gas
• added particle
the
F- OK
at new
, and
entropy stays
doesn't the
changa lowest
level
at Er
the the
energy ,
available state .
EF
=
µ limit
For classica
high T gas
0
<
µ
Rose
• gas added particle
the
F- Ok
at new
, entropy
doesn't tabes
the and
changa level at all athen
the energy
sama the
in state
partidos ground
0
=
µ limit
For classica
high T gas
0
<
µ
To :
sum up
CLASSI BOS
npr
npr CAL nl FERMI E
"
GAS GAS
GAS
EF • I
T t.ci
feste
, s s
classiche classiche
limit limit
structure
Definition periodici
8 and
. lattice
Bravais such
periodici structure
a as an
, wheme
crystal
infinite figure
is a
, atom
( example
for
base on
a on
itself
)
Molecule in
rrepeats space
a
indefinetelywithoutsupemposit.com
perizie
in fashion
a . infinite
social
Considerino as an
a. .
perizie to
allons
structure
physics
its just terms
destrier in
pemiodicity
the
of and its
base .
definition
Theme 3 Bravais
of
are
lattice :
PHYSICA
1 L
. (
of points
set such
modes )
called
a has the
then
each
that of sama
firrst
configuration neighbors
of .
MATHEMATICAL
2 .
. points generated by
of
set
a :
È mia (
mia è in )
3D
+
+ space
= ma }
,
,
uvheme Z
c-
mi independent
è nectaris
lineare
i primitive vechoms
called .
SYMMETRY
3 . I
considerino vector
translated
as ,
lattice
Rimarrai le
the con
define collection of
the
as indipendente transazione
lineare make
that the lattice
aectoms
• itself
overlap .
discount of
a set nonplanarn
with
closed
vertono inesperti
and
operations of
the
to seem .
difference
lahhiees
Amarmi
9 ZD
. possible
In 5
theme Bravais
ZD are
lattica : • •
: •
: !
a •
a &
^ I →
@
> @
@
@ • g
SQUARE RECTANGULAR ED
CENTER
RECTANGULAR
§ • • •
A •
q •
,
a >
→ • •
• ao a
e HEXAGONAL
OBLIQUE structure
Note the is
honeycomb
: NOT lattice
Bravais
a .
10 elementary
Definition basis all
,
. periodici structure
of a .
Seitz cell
Wigner - . objects
collection of phpsical
Base : that
( i. Molecular
atoms )
e ,
. itself
rrepeahs at emery
point
lattice . figure
unit cell geometriche
(
Elementary : trranslated
that lattice
all
over
points fills up
completely
space .
Shapes
Note not all
:
tessellate space
can pentagon
( for example :
call
Wigner Seitz :
- lattice
all centene
is
W
a s on
- a
points
point all
the
is in
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