Risk assessment as a tool for the sustainable management of contaminated
sites
potentially contaminated site
A is an area where concentrations exceeding the threshold values and can
caused potential risk to human health, ecosystems, or the environment. A site investigation and
characterization are a process of information and data to assess the conditions and characteristics of a specific
area and to collect the essential details about the geology, hydrogeology,
environmental conditions and other relevant factors. The main kind of investigations:
Environmental Investigation
• : presence of contaminants in soil and groundwater.
Hydrogeological Investigation
• : understanding the groundwater conditions
Geotechnical Investigation
• : assessing the soil/rock conditions
Types of investigations:
• Available documentation analysis
• On-site investigations
• Laboratory tests
Environmental matrices
1. Unsaturated superficial soil (0-1 m b.g.s.)
2. Unsaturated deep soil (below 1 m b.g.s.)
3. Groundwater
4. Interstitial gases (in the unsaturated soil)
How to assess contamination?
The traditional approach is based on the comparison between the
screening values
measured levels in soil and groundwater with
(are set close to or equal to background values to provide the
maximum degree of protection). Scientists were asked to derive
what are now called risk-based land management strategies:
reduce levels of pollutants, remediation targets are now based on
acceptable levels of risk for the intended land use, based on
environmental and human health risks.
Risk assessment allows to:
Estimate the potential risks for humans and the
• environment posed by the hazardous substances or
chemicals found at a property.
Establish a safe level of risk
• for humans and the
environment in order to define the clean-up objective
In Italy, the Legislative Decree n. 152/06 defines the screening levels CSC whereas risk-based threshold values
CSR.
Risks :
= ×
ℎ
= ×
Toxicity: Dose-Response Curves
Non-carcinogenic contaminants follow the threshold model: below certain doses the possible damage
Carcinogenic is assumed that
quickly becomes null (or negligible). contaminants follow the linear model: it
every dose poses a risk. For carcinogenic contaminants, the choice of the acceptable risk level is a
political choice regarding the incremental risk of tumors.
Conceptual Site Model
Conceptual Site Model (CSM)
The is a
representation of the (biological), physical and
chemical processes that determine the ways that
contaminants move from sources through the
environmental media to environmental receptors.
Contamination Sources
Primary contamination sources distinguished
between:
• Unsaturated zone:
• Surface soil (SS) ≤ 1 m b.g.l. depth;
•
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